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Table B.1 Selected Physical Property Data! SG ABa(Tm) SBT) (Abe) (AB Compound Formula Mol Wt. (204) Tm(C) kJlmol TyCC) KJmol TAKY Platm) — klmol KJ/mol Acetaldehyde CH;CHO 4405 07838 1237 e 20.2 251 461.0 -— —1662g) — —11924(g) Acetic acid CH;COOH 6005 1.049 16.6 12.09 1182 24.39 5948 571 —486.18(1) — —87L69I) —43815(g) — —919.73g) Acetone GHO 5808 0.791 -95.0 5.69 560 302 5080 470 -2482(1) — —17857(1) -216.7g) —1821.4(g) Acetylene GH, 2604 — — = -81.5 176 309.5 616 +226.75(8) —1299.6(g) Ammonia NH; 1703 — -78 5.653 3343 23351 4055 113 —67.20(1) 46198) — —382.58(g) Ammonium — NH,0H 3503. — — — — — = = —366.48(aq) — hydroxide Ammonium — NH;NO; 8005 17285 169.6 54 Decomposes at 210ºC —365.14(0) o nitrate —399.36(aq) Ammonium — (NH,)SO, 13214 1.769 s13 — Decomposes at 513ºC —11793(0) sulfate after melting —11731(ag) Aniline CH;N 9312 1.022 -63 ss 1842 ass 699 s24 — — Benzaldehyde CHsCHO 10612 1.046 —260 seas 179.0 38.40 = E -8883(1) — —3520.0(1) —40.04(g) — Benzene GHs 7811 0.879 5.53 9.837 8010 30765 5626 486 +48.66(1) —3267.6(1) +82.93(g) —3301.5(g) Benzoicacid — GHO; 12212 126618 1222 — 249.8 o — ms — —3226.7(g) Benzylalcohol C,HsO 108.13 1.045 -154 — 205.2 — — — — =3741.8(1) Bromine Bn 159.83 3.119 -14 10.8 58.6 310 s84 102 o(1) — 12-Butadiene CsHg 54090 — —1365 = 101 — 446 — — = 1,3-Butadiene CHs 5409 — -109.1 = -46 = 425 429 — mm n-Butane Cio sg&12 — —138.3 4.661 -06 22305 42517 3747 470) 285560) -1247g) — —28785(g) Isobutane Cilho s812 — —159.6 4540 1173 21292 4081 360 -1584(1) — —28490(1) A -134.5(g) —2868.8(g) 1-Butene CiHs s610 — — —1853 38480 625 21916 4196 397 +117g) —2718.6(g) Calcium Cac, 6410 22218 2300 — — — a ais —62.76(c) = carbide Calcium Caco; 10009 2.93 Decomposes at 825ºC —1206.9(c) — carbonate Calcium CaCh 110.99 21529 782 28.37 >1600 es = = —794.96(c) — chloride Table B.1 (Continued) sG AD AÔAT! (sBef (ABS Compound Formula Mol. Wt. (20%/4º) Ta((C) kJ/mol TC)! kJmol T(K) Po(atm) kJ/mol kJ/mol Calcium Ca(0H), 7410 2.24 (—H,0 at 580ºC) —986.59(c) — hydroxide Calcium oxide | CaO 5608 3.32 2570 so 2850 — = — —635.6(c) — Calcium Cas(POs) 31019 314 1670 — — — Em — -a138(0) — phosphate Calcium CaSiO; 116.17 2.915 1530 48.62 — — — — —1584(c) — silicate Calcium CaSOs 13615 2.96 — — — — — — —1432.7(c) — sulfate —1450.4(aq) Calcium CaSO,2H,0 17218 2.32 (-1.5 H,0 at 128ºC) — — — —2021(c) — sulfate (gypsum) Carbon c 12010 2.26 3600 46.0 4200 — — — Oc) —393.51(c) (graphite) Carbon Co, 44.01 — —56.6 8.33 (Sublimes at —78ºC) 304.2 72.9 —412.9(1) — dioxide at 5.2 atm —393.5(g) — Carbon cs 76.14 1261220 1121 4.39 46.25 26.8 552.0 78.0 +87.9(1) —1075.2(1) disulfide +115.3(g) 1102.6(g) Carbon co 28.01 — —205.1 0.837 —191.5 6.042 133.0 34.5 —110.52(g) —282.99(g) monoxide Carbon CCl 153.84 1.595 —22.9 2.51 76.7 30.0 556.4 45.0 —139.5(1) —352.2(1) tetrachloride —106.:7(8) —385.0(g) Chlorine Ch 70.91 — —101.00 6.406 34.06 20.4 417.0 761 o(g) — Chlorobenzene CsHsCI 112.56 1.107 -45 — 132.10 36.5 632.4 44.6 — — Chloroethane GHsCl See ethyl chloride “Adapted in part from D. M. Himmelblau, Basic Principles and Calculations in Chemical Engineering, 3rd Edition, 1974, Tables D.1 and Fl. Adapted by permission of Prentice-Hall, Inc., Englewood Cliffs, NJ. *Melting point at 1 atm. “Heat of fusion at Ty and 1 atm. “Boiling point at 1 atm. “Heat of vaporization at 7% and 1 atm. “Critical temperature. “Critical pressure. *Heat of formation at 25ºC and 1 atm. “Heat of combustion at 25ºC and 1 atm. Standard states of products are CO,(g), H>O(I), SO>(g), HCl(ag), and No(g). To calculate AR? with H,O(g) as a product, add 44.01n, to the tabulated value, where n, = moles H;O formed/mole fuel burned. *To convert AB to kcal/mol, divide given value by 4.184; to convert to Btu/lb-mole, multiply by 430.28. (continued) Table B.1 (Continued) SG SAT) A (To) (sabe (AB Compound Formula Mol. Wt. (20/49) Ta(C)P KkJímol TC)! KJmol T(KY Paim)? KJmol kJ/mol n-Heptane CH 100.20 0.684 —90.59 14.03 98.43 31.69 540.2 270 —224.4(1) —4816.9(1) —BT8(g) — —4853.5(g) n-Hexane CH 86.17 0.659 —95.32 13.03 68.74 28.85 507.9 29.9 —198.8(1) —4163.1(1) 16729) —4194.8(g) Hydrogen H, 2.016 Es —259.19 012 -252.76 0904 33 128 o(g) —285.84(g) Hydrogen HBr 80.92 = —86 es -67 = — ia —36.23(g) — bromide Hydrogen HCl 36.47 — —114.2 1.99 —85.0 16.1 324.6 81.5 —92.31(g) — chloride Hydrogen HCN 27.03 — —14 — 26 — — a +130.54(g) = cyanide Hydrogen HF 20.0 — —83 — 20 — 503.2 — —268.6(g) — fluoride —316.9(aq, — 200) Hydrogen Hs 34.08 — -85.5 2.38 —60.3 18.67 3736 889 —19.96(g) —562.59(g) sulfide Iodine b 2538 493 113.3 — 184.2 — 826.0 — O(c) — Iron Fe 55.85 771 1535 151 2800 354.0 — — O(c) = Lead Pb 20721 AL33PPPO 3274 510 1750 179.9 — o(c) — Lead oxide PbO 232 95 886 11.7 1472 213 — -— —219.2(c) == Magnesium Mg 2432 1.74 650 92 1120 131.8 — — O(c) — Magnesium MgCh 9523 23255 n14 431 1418 136.8 — — —641.8(c) — chloride Magnesium Me(OH), 5834 24 Decomposes at 350ºC — == hydroxide Magnesium MgO 4032 3.65 2900 TIA 3600 ca — — —601.8(c) — oxide Mercury Hg 200.61 13.546 —38.87 = —356.9 — = o(c) — Methane cH, 16.04 — —182.5 0.94 —161.5 8179 19070 458 —74.85(g) —890.36(g) Methyl GHO, 7408 0.933 —98.9 — 571 506.7 46.30 =409.4(1) —1595(1) acetate Methyl alcohol CH30H 32.04 0.792 —97.9 3.167 64.7 35.27 513.20 78.50 —238.6(1) 726.6(1) (Methanol) —201.2(g) —764.0(g) Methyl CH5N 3106 06991" —927 es -69 ess 4299 7360 —28.0(g) —1071.5(1) amine Methyl cH;CI 50.49 = -979 us -24 no 4161 6580 —81.92(g) — chloride (continued) Table B.1 (Continued) sG ABo(Ta)S ABAS (AByts (ABS Compound Formula Mol. Wt. (204º) Tm(C) kJlmol TAC) kJimol TAK) Patmy kJ/mol kJ/mol Methylethyl C,HsO 7210 0.805 -871 no 782 32.0 — ess — —2436(1) ketone Naphthalene CyoHs 128.16 1.145 80.0 — 217.8 — — — — —5157(g) Nickel Ni 58.69 8.90 1452 — 2900 — — — O(c) sm Nitric acid HINO; 63.02 1.502 -41.6 10.47 86 30.30 — — —173.23(1) = —206.57(aq) Nitrobenzene C5H50,N 123.11 1.203 5.5 — 210.7 — el — — —3092.8(1) Nitrogen N, 28.02 — —210.0 0.720 —195.8 5.577 126.20 35 O(g) — Nitrogen NO, 46.01 — =93 7.335 21.3 14.73 431.0 100.0 +33.8(g) [= dioxide Nitric oxide NO 30.01 — —163.6 2.301 -151.8 13.78 179.20 65.0 +90.37(g) — Nitrogen NOs 108.02 16318 30 — 47 — — — — — pentoxide Nitrogen NO, 92.0 1.448 = — 211 — 431.0 99.0 +9.3g) — tetraoxide Nitrous NO 44.02 1226” -911 — —88.8 — 309.5 71.70 +81.5(g) — oxide n-Nonane CH 128.25 0.718 —53.8 — 150.6 — 595 23.0 —229.0(1) —6124.5(1) — —6171.0(g) n-Octane CsHig 114.22 0.703 —570 — 125.5 — 568.8 24.5 —249.9(1) —5470.7(1) —208.4(g) —5512.2g) Oxalic acid CGH,04 90.04 1.90 Decomposes at 186ºC — — —826.8(c) —251.9(s) Oxygen O, 32.00 — —218.75 0.444 —182.97 6.82 154.4 49.7 o(g) — n-Pentane CH 7215 0.6318º —129.6 8.393 3607 25.77 469.80 33.3 —173.0(1) —3509.5(1) -1464(2) — —3536.1(g) Isopentane CGHy RAS Ge” 1601 — 211 Em 46100 329 —1793(1) —3507.5(1) = -1520(g) — —3529.2(g) 1-Pentene CH 70.13 0.641 —165.2 4.94 29.97 474 39.9 —20.9g) —3375.8(g) Phenol CHs50H 94.11 1,071 42.5 11.43 181.4 — 692.1 60.5 —158.1(1) —3063.5(s) —90.8(g) — Phosphoric HsPO4 98.00 1,83418 423 10.54 (-IHOat213ºC) — — es =12811(c) — acid ) —1278.6(aq, ae E 1H,0) Phosphorus P, 123.90 2.20 5908 aim 81.17 Ignites in air, 725ºC e: — —17.6(c) ta (red) e) Table B.1 (Continued) SG ABm(Tm) ABLTo)oS (Abe (AB) Compound Formula Mol. Wt. (204º) Ty(C) kJ/mol TOC)! kJ/mol TAK)” Po(atmy kJ/mol kJ/mol Sodium Na:S0; 15811 1.667 — — — — — — =—117.1(c) — thiosulfate Sulfur Ss 256.53 207 3 10.04 444.6 83.7 — — Oc) — (rhombic) Sulfur Sg 256.53 1.96 119 14.17 444.6 83.7 — — +0.30(c) = (monoclinic) Sulfur SO, 64.07 — —75.48 7.402 —10.02 24.91 430.7 718 —296.90(g) =— dioxide Sulfur SO; 80.07 — 16.84 25.48 43.3 41.80 491.4 83.8 —395.18(g) — trioxide Sulfuric HSO4 9808 1.834 1035 9.87 Decomposesat 340ºC — — -811.32(1) — acid —907.51(aq) — Toluene GH 92.13 0.866 —94.99 6.619 110.62 33.47 593.9 40.3 +12.00(1) —3909.9(1) +50.00(g) —3947.9(g) Water HO 18.016 1.009 0.00 6.0095 100.00 40.656 647.4 218.3 —285.84(1) — —241.83(g) — m-Xylene CHyo 106.16 0.864 —47.87 11.569 139.10 36.40 619 34.6 —25.42(1) —4551.9(1) +1724(g) —4594.5(g) o-Xylene CsHy 106.16 0.880 —25.18 13.598 144.42 36.82 631.5 35.7 —24.44(1) —4552.9(1) +18.99(g) —4596.3(g) p-Xylene CH 106.16 0.861 13.26 1711 138.35 36.07 618 33.9 —24.43(1) —4552.91(1) 1795(g) —4595.2(g) Zine Zn 65.38 7.140 419.5 6.674 907 114.77 — — Oc) — 
