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These are the Lecture Slides of Thin Film Materials Processing which includes Vaporization, Vapor Pressure Curves, Thermal Desorption, Molecular Binding Energy, First Order Desorption, Desorption Rate, Real Surfaces, Diffusion of Gas Particles etc. Key important points are: Vacuum Technology, Gas Flow, Knudsen’s Number, Reynolds’ Number, Flow Regimes, Quantity of Gas, Molecular Flow, Tube of Zero Length, Viscous Flow, Hagan-Poiseuille Equation, Laminar Flow
Typology: Slides
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Vacuum Technology
Page 2
Vacuum Technology
Page 3
d d d
Vacuum Technology
Page 5
Laminar Viscous Flow - Ordered flow of gas in streamlines.Dominated by gas-gas collisions
Kn < 0.01, R < 1200
Molecular Flow - Dominated by gas-wall collisions. Assume diffusereflection at surfaces (molecules are re-emitted in a directionindependent of the incident direction). Gas molecules do not collidewith eachother.
Kn > 1, R < 1200
Turbulent Flow -
Kn < 0.01, R > 2200
Transition Flow - Gas is neither viscous nor molecular. Flow isdominated by both gas-gas collisions and gas-wall collisions
1 > Kn > 0.
Vacuum Technology
Page 6
Throughput (Q) - Quantity of gas (the volume of gas at a knownpressure) that passes a plane in a known time. Units = Pa-m
3
/s or
Watts (energy flow -- energy it takes to transport the molecules acrossa plane)
Q = P(dV/dt) where: P=pressure and dV/dt = volumetric flow rate
Mass Flow - The quantity of a substance (kg) that passes a plane in aknown time. Units = kg/s
Molecular Flow - The quantity of a substance (number of moleculesN) that passes a plane in a known time. Units = N/s
Conductance - The ability of an object to transport gas between twopressures regimes. Units = m
3
/s
Analogous to ohms law -- 1/R= I/V
1
2
Vacuum Technology
Page 8
contracta"
vena "
flow
gas
of
speed
high
the
of
because
area
sectional
cross
the
reduces
ch
factor whi a
is
(triatomic
and , )
(monatomic
for
species),
(diatomic (^4). 1
'
1
2 1
1 2
1
2 1
1
2 1
1 2
'
1
−
−
where
for
kT m
P V
γ
γ
γ γ
γ
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Vacuum Technology
Page 9
of t
independen
is
Flow
air
for
1 1
1 2
'
1
1
(^21)
−
−
γ
γ
γ
kT^ m
Vacuum Technology
Page 11
Viscous Flow – Long Round Tubes
)
(
2
128
2
1
2
1
4
P P P P l d Q
−
=
η
π
(
)
2
)
(
10
38 . 1
2
1
4
6
Pascals
P
P
l
meters
d
x
l s
C
=
Hagan-Poiseuille Equation
Vacuum Technology
Page 12
Viscous Flow – Long Round Tubes
not position dependent
U/U
sound
< 1/3 (ie non-choked flow)
Vacuum Technology
Page 14
Molecular Flow – Long Round Tube
l d
v
C
3
π 12
=
)
(
)
(
121
m
l
m
d
s m
C
=