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Thermodynamics 1 sta.maria, Cheat Sheet of Thermodynamics

Thermodynamics 1 Sta. Maria Hipolito

Typology: Cheat Sheet

2023/2024

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Thermodyna
mics
H I P O L I T O S T A. M A R I A
B S E C E 1-1 (Bridging)
1
S H A N E B U R A G A
M A I R E N E C A B A R I O S
N O A H C H R I S T O P H E R T A N
L Y N G A Y T O
J O H N C E R D A
J E N E R I E T U D T U D
L H Y N I E T A N A Y
R H I A M A Y F L O R E S
C A R L D A V I D L A P I R A
R U T H L I M B A G O
J O H N O L I V A
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Thermodyna

mics

H I P O L I T O S T A. M A R I A

B S E C E 1-1 (Bridging)

S H A N E B U R A G A

M A I R E N E C A B A R I O S

N O A H C H R I S T O P H E R T A N

L Y N G A Y T O

J O H N C E R D A

J E N E R I E T U D T U D

L H Y N I E T A N A Y

R H I A M A Y F L O R E S

C A R L D A V I D L A P I R A

R U T H L I M B A G O

J O H N O L I V A

Basic Principles, Concepts and Definition Thermodynamics is that brach of the physical sciences that treats of various phenomena of energy and the related properties of matter, especially of the laws of transformation of heat into other forms of energy and vice versa.

Systems of Units

Newton’s law states that “the acceleration of a particular body is directly proportional to the resultant force acting on it and inversely proportional to its mass.” a= kF m

, F=

ma k , k= ma F k is a proportionality constant Systems of units where k in unity but not dimensionless: cgs system: 1 dyne force accelerates 1 g mass at 1 cm/s^2 mks system: 1 newton force accelerates 1 kg mass at 1 m/s^2 fps system: 1 lb force accelerates 1 slug mass at 1 ft/s^2 k = 1 gm ∙ cm dyne ∙ s 2 k^ =^1 k gm ∙ m newton ∙ s 2 k = 1 slug∙ ft lb (^) f ∙ s 2 Systems of units where k is not unity: If the same word is used for both mass and force in a given system, k is neither unity nor dimensionless. 1 lb force accelerates a 1 lb mass at 32.174 ft/s^2 1 g force accelerates a 1 g mass at 980.66 cm/s^2 1 kg force accelerates a 1 kg mass at 9.8066 m/s^2

F=

m k a 1 pound = (1 slug)(1 ft/s^2 ); 1 slug= 1 lb f ∙ s 2 ft F is force in pounds m k is mass in slugs a is acceleration in ft/s^2 Mass and Weight The mass of a body is the absolute quantity of matter in it. The weight of a body means the force of gravity Fg on the body. m k

F

a

Fg g Where g = acceleration produced by force Fg a = acceleration produced by another force F At or near the surface of the earth, k and g are numerically equal, so are m and Fg Problems:

  1. What is the weight of a 66-kgm man at standard condition? Solution m = 66 kgm g = 9.8066 m/s^2 Fg= mg k

[ 66 kgm ] [9.^ m s

2 ]

kgm ∙ m kgf ∙ s 2 = 66 kgf

  1. The weight of an object is 50 lb. What is its mass at standard condition? Solution

Fg = 50 lbf g = 32.174 ft/s^2 m= Fg k g

[^50 lbf ] [

lbm ∙ ft lbf ∙ s (^2) ]

ft s 2 = 50 lbm

  1. Five masses in a region where the acceleration due to gravity is 30.5 ft/s^2 are as follows: m 1 is 500 g of mass; m 2 weighs 800 gf; m 3 weighs 15 poundals; m 4 weighs 3 lbf; m 5 is 0.10 slug of mass. What is the total mass expressed (a) in agrams, (b) in pounds, and (c) in slugs Solution g = (30.5 ft/s^2 )(12 in/ft)(2.54 cm/in) = 929.64 cm/s^2 (a) (^) m 2 =^ Fg 2 k g

[ 800 g¿ ¿ f ] [

gm ∙ cm gf ∙ s (^2) ]

cm s 2 =843.91 gm ¿ m 3 k

Fg 3 g

lbm ∙ ft s 2

ft s 2 =[ 0.49 lbm ] [

gm lbm ] =222.26 gm m 4 = Fg 4 k g

[ 3 lbf ] [

lbm ∙ ft lbf ∙ s (^2) ]

ft s 2 [

gm lbm ] =1435.49 gm m 5 k =( 0.10 slug) [

lbm slug ][

gm lbm ] =1459.41 gm Total mass = m 1 + m 2 + m 3 + m 4 + m 5 = 500 + 843.91 + 222.26 +1435.49 + 1459. = 4461.07 gm (b) Total mass = 4461.07 g m

gm lbm

lbm

Specific Volume, Density and Specific Weight The density ρ of any substance is its mass (not weight) per unit volume ρ= m v The specific volume v is the volume of a unit mass. v=

V

m

ρ The specific weight γ of any substance is the force of gravity on unit volume γ = Fg V Since the specific weight is to the local acceleration of gravity as the density is to the standard acceleration, γ /g = ρ/k, conversion is easily made; ρ= γk g ∨γ= ρg k At or near the surface of the earth, k and g are numerically equal, so are ρ and γ. Problems

  1. What is the specific weight of water at standard condition? Solution

g = 9.8066 m/s^2 ρ= 1000 kgm m 3 γ = ρg k

[

kgm m (^3) ][9.^ m s (^2) ]

kgm ∙ m kgf ∙ s 2

kgf m^3

  1. Two liquids of different densities (ρ 1 = 1500 kg/m^3 , ρ 2 = 500 kg/m^3 ) are poured together into a 100-L tank, filling it. If the resulting density of the mixture is 800 kg/m^3 , find the respective quantities of liquids used. Also, find the weight of the mixture; local g = 9.675 mps^2 Solution Mass of mixture, mm = ρmvm = (800 kg/m^3 )(0.100 m^3 ) = 80 kg m1 + m 2 = mm ρ 1 V 1 + ρ 2 V 2 = mm 1500 V 1 + 500 V 2 = 80 (1) V1 + V 2 = 0.100 (2) solving equations (1) and (2) simultaneously V 1 = 0.03 m^3 V 2 = 0.07 m^3 m 1 = ρ 1 V 1 = (1500 kg/m^3 ) (0.03 m^3 ) = 45 kg m 2 = ρ 2 V 2 = (500 kg/m^3 ) (0.07 m^3 ) = 35 kg weight of mixture, Fgm= mm g k

[ 80 kgm ] [9.^ m s

2 ]

kgm ∙ m kgf ∙ s 2 =78.93 kgf

mechanism is of course enclosed in a case, and a graduated dial, from which the pressure is read, and is placed under the index hand. Gage Pressure Problem A 30-m vertical column of fluid (density 1878 kg/m^3 ) is located where g = 9.65 mps^2. Find the pressure at the base of the column. Solution (p = 0, Pg = Po) (p = po – pg) (pg = 0, p = po) (p = po + pg) p = po + pg pg=γ hg = ρg hg k

g hg kv pg= Fg A

γV A

γA hg A

pg= gρhg k

[

m s (^2) ][^1878 kgm m (^3) ] 1 kgm ∙ m N ∙ s 2 ( 30 m) ¿ 543,

N

m 2 ∨543.68^ kPa^ (^ gage^ ) Atmospheric Pressure A barometer is used to measure atmospheric pressure. Where ho = the height of column of liquid supported by atmospheric pressure Po Problems

  1. A vertical column of water will be supported to what height by standard atmospheric pressure. Solution At standard condition γ (^) w=62. lb ft 3 po=14.7^ psi
po =γ Hg hg =( sp gr ) Hg ( γ w ) ( ho )

[

lb ft (^3) ]¿^ ¿ where ho = column of mercury in inches then, pg=0.491^ hg lb ¿. 2 and, p=0.491h^ lb ¿. 2 Problems

  1. A pressure gage registers 40 psig in a region where the barometer is 14.5 psia. Find the absolute pressure in psia, and kPa. Solution p = 14.5 + 40 = 54.5 psia 1 kgm = [ 1 kg¿¿ m][ 2. lbm kgm
]

lbm slug =0.06853 slug ¿

m s 2 =[^1 m s (^2) ][3.^ ft m ]

ft s 2 F= ma k =( 0.06863 slug) [

ft s (^2) ]=0.2248^ lbf 1 newton = 0.2248 lbf 1 lbf = 4.4484 newtons 1 lb ¿

( 1 lb) [

N

lb ][

m ] ¿ 2 1 lb ¿

2 =^6895
N

m 2 p=[54. lb ¿ (^2) ] [

N

m 2 lb ¿. 2 ] =375,780 Pa∨375.78 kPa

  1. Given the barometric pressure of 14.7 psia (29.92 in. Hg abs), make these conversions: (a) 80 psig to psia and to atmosphere (b) 20 in. Hg vacuum to in. Hg abs and to psia, Solution (a) p=^ po+^ pg=14.7^ +^80 =94.7^ psia

t ° F− 32 212 − 32

t ° C− 0 100 − 0 t ° F=

t ° C+ 32 t ° C=

t ° F− 32 Absolute temperature is the temperature measured from absolute zero. Absolute zero temperature is the temperature at which all molecular motion ceases. Absolute temperature will be denoted by T, this T ° R=t ° F+ 460 , degreed Rankine T K =t ° C+ 273 , Kelvin Degrees Fahrenheit (ºF) and degrees Centigrade (ºC) indicate temperature reading (t). Fahrenheit degrees (Fº) and Centigrade degrees (Cº) indicate temperature change or difference (∆t). 180 Fº = 100 Cº 1 F °=

C °
1 C °=
F °

It follows that, 1 F °= 1 R ° and 1 C °= 1 K °

  1. Show that the specific heat of a substance in Btu/(lb) (Fº) is numerically equal to cal/(g)(Cº). Solution

Btu ( lb) ( F °)

[ Btu ]

[

cal Btu ] [ lb] (^) [ 454 g lb ] [ F ° ][

5 C °

9 F ° ] 1 Btu ( lb) ( F °)

cal ( g ) ( C ° ) Conservation of Mass The law of conservation of mass states that mass is indestructible. The quantity of fluid passong through a given section is given by the formula = Av =

v

Av v = Avρ Where = volume flow rate A = cross sectional area of the stream v = average speed = mass flow rate Applying the law of conservation of mass, = A 1 v 1 v 1

A 2 v 2 v 2 A 1 v 1 ρ 1 = A 2 v 2 ρ 2 Problems

  1. Two gaseous streams enter a combining tube and leave as a single mixture. These data apply at the entrance section: For one gas, A 1 = 75 in.^2 , v 1 = 500 fps, v 1 = 10 ft^2 /lb For the other gas, A 2 = 50 in.^2 , ṁ 2 = 16.67 lb/s ρ 2 = 0.12 lb/ft^3 At exit, v 3 = 350 fps, v 3 = 7 ft^3 /lb. Find (a) the speed of v 2 at section 2, and

Conservation of Energy Conservation of Energy Gravitational Potential Energy (P) The gravitational potential energy of a body is its energy due to its position or elevation. Kinetic Energy (K) The energy or stored capacity for performing work possessed by a moving body, by virtue of its momentum is called kinetic energy. Internal Energy (U,u)

Internal energy is energy stored within a body or substance by virtue of the activity and configuration of its molecules and of the vibration of the atoms within the molecules. u = specific internal energy (unit mass) Δ u = u 2 – u 1 U = mu = total internal energy ( m mass) Δ U = U 2 -U 1 Work (W) Work is the product of the displacement of the body and the component of the force in the direction of the displacement. Work is energy in transition; that is is exists only when a force is “moving through a distance”. Work of a nonflow System The area under the curve of the process on the pV plane represents the work done during a nonflow reversible process. Work done by the system is positive ( outflow of energy) Work done on the system is negative (inflow of energy) Flow Work (Wf) Flow work or flow energy is work done in pushing a fluid across a boundary, usually into or out of a system.