1252 Alcohol, Phenol and Ethers
1.
CBACH
OH
HCCH
O
CHCHMgPBr 223
3
|
3
D
OH 2
Here, D is [BVP 2004]
(a)
32
3
|
3CHCHO
CH
HCCH
(b)
32
3
|
3CHCH
CH
HCOCH
(c)
OHCHCH
CH
HCCH 22
3
|
3
(d)
OHCH
CH
HCCHCH 2
3
|
23
2. Phenol is more acidic than [Pb. CET 2003]
(a) (b)
(c)
22HC
(d) Both (a) and (c)
3. In the reaction,
)()( 3
2356 AOCOCHCHOHC COONaCH
product (A)
is [Pb. CET 2000]
(a) Acetaldehyde (b) Cinnamic acid
(c)
-nephthol (d) Phenol
4. The correct order of ease of dehydration of
following is
[CPMT 2004]
(a) I > II > III (b) III > II > I
(c) I > III > II (d) III > I > II
5.
5
PCl
reacts with a compound containing[Pb. CET 2002]
(a)
3
SO
group (b) – OH group
(c)
3
NO
group (d) – NO group
6. Cumene process is the most important
commercial method for the manufacture of
phenol. Cumene is [KCET 2004]
(a) 1-methyl ethyl benzene (b) Ethyl benzene
(c) Vinyl benzene (d) Propyl benzene
7. The compound X in the reaction [Roorkee 1999]
is
(a) (b)
(c) (d)
8. Reaction
OHCH
OH
OHCH
OH
OCH
OH
2
2
or base acid
2
is called [MP PET 2003]
(a) Lederer Manasse reaction
(b) Claisen condensation
(c) Benzoin condensation
(d) Etard reaction
9. When phenol is reacted with
3
CHCl
and
NaOH
followed by acidification, salicyldehyde is
obtained. Which of the following species are
involved in the above mentioned reaction as inter
mediate [DCE 2000]
(a) (b)
(c) (d) All of these
10. The order of solubility of alkanols in water is
(a) Propanol < Butanol > Pentanol
(b) Propanol > Butanol > Pentanol
(c) Propanol > Butanol < Pentanol
(d) Propanol = Butanol = Pentanol
11. In the following compounds
OH
OCH3
NO2
OH
I
OH
II
OH
II
I
OH
ON
a
OH
COOH
+ CO2
K390
X
HCl
COONa
ON
a
COONa
ON
a
COOH
OCOON
a
O
3
CCl
H
O
2
CHCl
OH
CHCl
|
O
H
OH
(I
)
CH
3
OH
(I
I)
2
NO
OH
(II
I)
NO
2
OH
(IV
)
