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Properties of Metals: Structure, Classification, and Applications, Lecture notes of Chemistry

A comprehensive overview of the properties, structure, and classification of metals. It delves into the crystalline structure of metals, explaining how their atomic arrangement influences their properties. The document then classifies metals into ferrous and non-ferrous categories, outlining the characteristics and applications of each type. It also explores the relationship between structure and properties in non-ferrous metals, highlighting the importance of alloying for specific applications.

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2023/2024

Uploaded on 02/07/2025

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Course CHEM111E (Chemistry for Engineers)
Title of the
Module Unit III. Chemistry of Engineering Materials – Metals
Learning
Objectives
At the end of this module, the student shall be able:
a. To distinguish different types of fuels.
b. To calculate the amount of energy that can be derived from
fuels.
Content
I. Structure of Metals
II. Properties of Metals
III. Classification of Metals
Introduction
Metals, from the Greek word ‘’metallon” (mine or quarry), are used in various
aspects of our daily lives. Roughly 25% of the earth’s crust is comprised of metals
and due to this abundance and metals’ varied properties, they can be used in
construction, home appliances, tools, decorative items and jewelry, coinage and
more.
The history of refined metals is very long. The smelting and use of copper has
been show to date back to the Bronze age, at around 3500 B.C. Gold, silver,
meteoric iron, and lead have been in use earlier than that. The smelting of iron
dates back to around 1500 B.C. and subsequent developments of early forms of
steel followed at around 1200 B.C. Further discoveries of new types of metals and
the development of modern alloys from early simple steel alloys to more
complicated and specialized ones have happened over the years, to cater to
various needs and applications.
I. Structure of Metals
Almost all metallic elements are crystalline solids at room temperature.
Only cesium, gallium and mercury are not (with mercury being the only metal
that is not solid at room temp.). This means that atoms of metals and metallic
substances are arranged in an orderly and regular fashion.
Imagine the metal atoms to be identical spheres which are stacked together
in layers, each layer’s spheres slotting into the spaces between where the
spheres of the other layers come together, much like how fruits are stacked in
displays or how balls and cannonballs are stacked together.
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Course CHEM111E (Chemistry for Engineers)

Title of the Module

Unit III. Chemistry of Engineering Materials – Metals

Learning Objectives At the end of this module, the student shall be able: a. To distinguish different types of fuels. b. To calculate the amount of energy that can be derived from fuels. Content I. Structure of Metals II. Properties of Metals III. Classification of Metals Introduction Metals, from the Greek word ‘’metallon” (mine or quarry), are used in various aspects of our daily lives. Roughly 25% of the earth’s crust is comprised of metals and due to this abundance and metals’ varied properties, they can be used in construction, home appliances, tools, decorative items and jewelry, coinage and more. The history of refined metals is very long. The smelting and use of copper has been show to date back to the Bronze age, at around 3500 B.C. Gold, silver, meteoric iron, and lead have been in use earlier than that. The smelting of iron dates back to around 1500 B.C. and subsequent developments of early forms of steel followed at around 1200 B.C. Further discoveries of new types of metals and the development of modern alloys from early simple steel alloys to more complicated and specialized ones have happened over the years, to cater to various needs and applications. I. Structure of Metals Almost all metallic elements are crystalline solids at room temperature. Only cesium, gallium and mercury are not (with mercury being the only metal that is not solid at room temp.). This means that atoms of metals and metallic substances are arranged in an orderly and regular fashion. Imagine the metal atoms to be identical spheres which are stacked together in layers, each layer’s spheres slotting into the spaces between where the spheres of the other layers come together, much like how fruits are stacked in displays or how balls and cannonballs are stacked together.

Figure 1. metal atoms are stacked similarly to how we see fruit being stacked or how any large or heavy spheres are stored/arranged This arrangement is the most efficient as it minimizes the empty space between the spheres. Metal crystals have unit cells – the smallest section of a crystal lattice that still retails the overall structure and symmetry of the lattice – wherein the atoms are arranged in such close-packed structures. Most pure metals and metallic alloys naturally adopt one of these three arrangements which provide the closest packing structures: www.ggspdt.com Figure 2. The common structures of the unit cells of most metals (a) Hexagonal close-packed (hcp) structure. This crystal structure has atoms occupying all corners of a hexagonal prism and one atom at the center of each of the two hexagonal faces. (b) Face-centered cubic (fcc) structure. In this structure, there is one atom at the center of each of the six faces of the cube and eight atoms at each corner. (c) Body-centered cubic (bcc) structure. In this crystal structure, we can imagine eight of the metal atoms occupying all corners of a cube and another atom at the very center of the cube. These different structures affect certain metallic behaviors particularly strength and ductility. Because of the close-packed nature of the atoms, the attraction between the atomic nuclei and the surrounding electrons may occur in all directions and we can say that the bonding in metals in nondirectional; this means that upon the application of pressure, a metal will deform rather than

the BCC structure. Figure 4. How metallic crystal structure affects ductility III. Classification of Metals Ferrous vs. Nonferrous Metals This is the most general/broad classification of metals. Ferrous metals, as the name implies, contain iron (“ ferrum ” being the Latin name for iron). Iron (Fe) is a very abundant element and although difficult to find pure in nature, it is present in many minerals. It is also relatively cheap due to the fact that it is relatively easy to refine. When combined with other metals in alloys, or even by itself, it displays different properties which results in its versatility as an alloying component. Ferrous metals are also magnetic and strong but are prone to corrosion. Around 90% of all manufactured metals contain iron. Non- ferrous metals, like brass, on the other hand do not have iron in them. They do not have any magnetic properties. The most common non-ferrous metals used in the industry are Cu, Al, Zn, Sn, Pb, Co, and Ni. The non-ferrous metals and the alloys based on them have names that are based on their element’s names (e.g. copper alloy, aluminum alloy, etc.) FERROUS METALS Properties Uses Pig Iron/Crude Iron (92%iron, up to 3.5% C and other impurities)

  • First product in the smelting of iron - Cannot be welded - Can be hardened but not tempered - Brittle (not malleable) - Rarely used by itself - Mixed with other metals or elements in making steel Cast Iron (Iron with up to 2- 6.7% C)
  • Cannot be magnetized
  • Does not corrode easily unless exposed to saline water
  • Cannot be used in forging because it is
  • Making pipes and sanitary fittings
  • Making gates, lamp posts, railings, etc.
  • Making machinery parts and agricultural tools

a bit brittle Wrought Iron (iron with less than 0.08% C)

  • Magnetic
  • Ductile, malleable, tough
  • Not affected by saline water and can resist corrosion
  • Can be welded but fuses with difficulty - Tough materials such as rivets, bolts and nuts - Decorative/ ornamental iron works like gates, outdoor stairs, railings Steel (iron, small amounts of C + other elements in various %s) At present, over 3500 grades of steel are available in the market. a. Carbon steel
  • Low-carbon steel aka mild steel. (<0.25% C)
  • Medium-carbon steel (0.25-0.6% C)
  • High-carbon steel (0.6% C or greater) b. Alloy steel (iron with other alloying elements like Mn, Ti, Cu, Cr, Ni, Mo, W, V, etc.)
  • High tensile strength
  • High strength-to- weight ratio
  • High durability (harder than pure iron)
  • Other alloying metals are added to enhance various properties (weldability, ductility, corrosion resistance, etc.) depending on what the steel is needed for a. Carbon steel
  • Depending on C- content, can be used for moderate to high pressure applications
  • I-beams, metals for bridges, tubings, drill bits, etc. b. Alloy steels like stainless steel (high in chromium) are 200x more resistant to corrosion than mild steel so it is good for kitchen utensils and medical equipment.
  • tool steel (contains Mo, V, Co or W) has high hardness and can be used in chisels, etc.
  • some high-alloy steels are also used in the automotive and shipbuilding industries NON-FERROUS METALS Even though all metals share some similar mechanical properties, individually they have properties that may or may not be advantageous for certain applications. These individual properties can be exploited by mixing various metals in different proportions when creating alloys. Some of the most commonly used non-ferrous metals in the industry are:
  1. Structure of Metals a) Hexagonal close-packed (hcp) structure. Atoms occupying all corners of a hexagonal prism + one atom at the center of each of the two hexagonal faces. b) Face-centered cubic (fcc) structure. One atom at the center of each of the six faces of the cube + eight atoms at each corner. c) Body-centered cubic (bcc) structure. Eight metal atoms occupying all corners of a cube + 1 atom at the very center of the cube.
  2. Properties of Metals a) Metallic luster b) High thermal and electrical conductivity c) Malleability d) Ductility
  3. Classification of Metals Main classification of metals FERROUS NON-FERROUS
  • Pig iron
  • Cast iron
  • Wrought iron
  • Steel a. Carbon Steel b. Alloy Steel
  • Copper
  • Aluminum
  • Zinc
  • Tin
  • Lead
  • Cobalt
  • Nickel, etc. And their alloys References: Askeland, D. et. al. (2010). The Science and Engineering of Materials (6th Ed). Cengage Learning, Inc. Mortimer, Charles E. (1975). Chemistry: A Conceptual Approach (3rd ed.). New York: D. Van Nostrad Company. Russell, A. M; Lee, K. L. (2005). Structure–Property Relations in Nonferrous Metals. Structure-Property Relations in Nonferrous Metals. Hoboken, NJ: John Wiley & Sons.