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Chemical Reactions: Observations, Requirements, and Balanced Equations, Study notes of Law

Observations that suggest a chemical reaction has taken place, including the evolution of heat and light, production of a gas, and formation of a precipitate. It also lists requirements for writing a correctly balanced chemical equation, such as representing known facts, using the correct formulas, and satisfying the law of conservation of mass. examples and guidelines for balancing a chemical equation.

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Chapter 8
Objective 8-1-1 List three observations that suggest that a chemical reaction has taken
place.
A chemical equation represents, using symbols and
formulas, the identities and relative amounts of the
reactants and products in a chemical reaction.
2H2O (l) 2H2 (g) + O2 (g) (Balanced)
To know for certain that a chemical reaction has taken
place requires evidence that one or more substances have
undergone a change in identity.
Absolute proof of such a change can be provided only by chemical analysis of the
products. However, certain easily observed changes usually indicate that a chemical
reaction has occurred.
Possibly a reaction has Occurred when:
1. Evolution of heat and light. A change in matter that
releases energy as both heat and light is strong evidence
that a chemical reaction has taken place.
2. Production of a gas. The evolution of gas bubbles when
two substances are mixed is often evidence of a chemical
reaction.
3. Formation of a precipitate. Many chemical reactions take
place between substances that are dissolved in liquids. If a
solid appears after two solutions are mixed, a reaction has
likely occurred.
Precipitate: a solid that is produced as a result of a chemical
reaction in solution and that separates from the solution.
4. Color change. A change in color is often an indication of
a chemical reaction.
NOTE: None of these are absolute proof, only strong evidence.
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Chapter 8 Objective 8-1-1 List three observations that suggest that a chemical reaction has taken place. A chemical equation represents, using symbols and formulas, the identities and relative amounts of the reactants and products in a chemical reaction.

2H 2 O (l)  2H2 (g) + O2 (g) (Balanced)

To know for certain that a chemical reaction has taken place requires evidence that one or more substances have undergone a change in identity. Absolute proof of such a change can be provided only by chemical analysis of the products. However, certain easily observed changes usually indicate that a chemical reaction has occurred. Possibly a reaction has Occurred when:

1. Evolution of heat and light. A change in matter that

releases energy as both heat and light is strong evidence that a chemical reaction has taken place.

2. Production of a gas. The evolution of gas bubbles when

two substances are mixed is often evidence of a chemical reaction.

3. Formation of a precipitate. Many chemical reactions take

place between substances that are dissolved in liquids. If a solid appears after two solutions are mixed, a reaction has likely occurred. Precipitate: a solid that is produced as a result of a chemical reaction in solution and that separates from the solution.

4. Color change. A change in color is often an indication of

a chemical reaction.

NOTE: None of these are absolute proof, only strong evidence.

Objective 8-1-2. List three requirements for a correctly written chemical equation.

  1. The equation must represent known facts. All reactants and products must be identified, either through chemical analysis in the laboratory or from sources that give the results of experiments.
  2. The equation must contain the correct formulas for reactants and products. Example: there are several elements that exist as diatomic molecules in nature: Element Symbol Molecular formula Physical state at room temperature Hydrogen H H 2 gas Nitrogen N N 2 gas Oxygen O O 2 gas Fluorine F F 2 gas Chlorine Cl Cl 2 gas Bromine Br Br 2 liquid Iodine I I 2 solid

Symbols Used in Chemical Equations Reactants and Products Symbol Meaning ( s ) or ( cr ) solid or crystal ( l ) liquid ( g ) gas ( aq ) in aqueous solution (dissolved in water) solid precipitate^ product forms

 gaseous^ product^ forms

Word Equation: an equation in which the reactants and products in a chemical reaction are represented by words. methane + oxygen  carbon dioxide + water Formula Equation: represents the reactants and products of a chemical reaction by their symbols or formulas. CH4( g ) + O2( g )  CO2( g ) + H 2 O( g ) (not balanced)

Balancing an Equation: relative amounts of reactants and products represented in the equation must be adjusted so that the numbers and types of atoms are the same on both sides of the equation. This is carried out by inserting coefficients. Once it is balanced, a formula equation is a correctly written chemical equation. A coefficient is a whole number that appears in front of a formula in a chemical equation. Specifies the relative number of moles of the substance; if no coefficient is written, the coefficient is assumed to be 1. Objective 8-1-4. Balance a formula equation by inspection.

Two additional hydrogen atoms are needed on the right side of the equation. They can be added by placing the coefficient 2 in front of the chemical formula H 2 O. CH4( g ) + O2( g )  CO2( g ) + 2 H 2 O( g ) (not balanced) A coefficient multiplies the number of atoms of each element indicated in a chemical formula. Thus, 2H 2 O represents four H atoms and two O atoms. Now consider the number of oxygen atoms. There are four oxygen atoms on the right side of the arrow in the partially balanced equation. Yet there are only two oxygen atoms on the left side of the arrow. One can increase the number of oxygen atoms on the left side to four by placing the coefficient 2 in front of the molecular formula for oxygen. CH4( g ) + 2O2( g )  CO2( g ) + 2H 2 O( g ) (balanced) This results in a correct chemical equation, or balanced formula equation. Homework: Practice Problems Page 248

Significance of a Chemical Equation

  1. The coefficients of a chemical reaction indicate relative, not absolute, amounts of reactants and products. H2( g ) + Cl2( g )  2HCl( g ) 1 molecule H 2 : 1 molecule Cl 2 : 2 molecules HCl 1 mole H 2 : 1 mole Cl 2 : 2 moles HCl

  2. The relative masses of the reactants and products of a chemical reaction can be determined from the reaction’s coefficients. 1 mole H 2 : 1 mole Cl 2 : 2 moles HCl 2.02 g H 2 : 70.90 g Cl 2 : 72.92g HCl

  3. The reverse reaction for a chemical equation has the same relative amounts of substances as the forward reaction.

2 mol (72.92 g) of hydrogen chloride yield 1 mol (2.02 g) of hydrogen and 1 mol (70.90 g) of chlorine. 2HCl( g )  H2( g ) + Cl2( g )